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I greatly dislike iTunes but I can tell you from the experience of a friend who used to use it; he hated the sound quality of iTunes-ripped music. It sounded almost...metalic. So in the end, he used to use another CD ripper, and used to pick a format of .mp3. Either 192kbps or 320kbps was depending on the type of CD, but most ripping programs will check the content and pick the one that's most appropriate.
.mp3 in 320 in particular comes out wonderfully on the iPod.
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